CONTAMINATION IN CAMP POND AND CAMP WATER WELL FROM CHEMTURA'S GLCC LEAKING TAILBRINE POND, LEAKING INJECTION WELLS, AND LEAKING LANDFILLS
The EPA took some core samples
from the Camp Pond Sediment in July 1977. Analysis of these core samples shows
detection of Tetrabromobisphenol A
(Synonym: 4,4'-ISOPROPYLIDENEDIPHENOL) at 300 ug/Kg or 0.003
ppm.
Tetrabromobisphenol A is a flame
retardant made at GLCC-Central.
ON-SITE TOXIC RELEASE INVENTORIES FOR TETRABROMOBISPHENOL A AT GLCC-CENTRAL
ON-SITE TOXIC RELEASE INVENTORIES FOR 4,4'-ISOPROPYLIDENEDIPHENOL AT GLCC-CENTRAL
n-Butyl Alcohol
Aug 2004 Camp Water Well Sample contained
3220.0 ug/L or 3.22 ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR n-Butyl Alcohol AT GLCC-CENTRAL
Zinc
Nov 2003 Camp Water Well Sample contained 306 ug/L or 0.306 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 40.4 mg/kg or 40.4 ppm.
Aug 2003 Camp Pond Wrist Deep Surface Water Sample, Pathfinder Split, 24.99 ug/L
or 0.02499 ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR ZINC AT GLCC-CENTRAL
Unknown Sulfur Compound
Retention Time 10.78
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 2,900 ug/kg or 2.9 ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Unknown Sulfur Compound
Retention Time 10.85
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 2,700.0 ug/kg or 2.7 ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Unknown Sulfur Compound
Retention Time 10.89
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 3,600.0 ug/kg or 3.6 ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Cyclic octaatomic sulfur
(10544-50-0) S8
Aug 2003 Camp Pond Sediment Sample contained 9,300 ug/kg or 9.3 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 25,000 ug/kg or 25.0
ppm.
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Sulfur, mol. (S8)
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T.
14.13 Est Conc 17.43 ug/ml, or 17.43 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S |
256 |
S8 |
010544-50-0 |
95 |
|
2 |
Manganese, [[1,2-ethanediylbis[carbamodithioato]](2 |
265 |
C4H6MnN2S4 |
012427-38-2 |
90 |
|
3 |
Sulfur $$ Sulfur, precipitated $$ S |
256 |
S8 |
007704-38-9 |
72 |
|
4 |
N-(2-Hydroxyethyl)-N'-[2'-(methoxy |
255 |
C10H13N3O3S |
000000-00-0 |
64 |
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Sulfur, mol (S8)
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T. 14.11 Est Conc 8.28 ug/ml or 8.28 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Sulfur, mol (S8) (CAS) $$ OCTA -SULFUR $$ s8 $$ Sul |
256 |
S8 |
010544-50-0 |
97 |
|
2 |
N-(2-Hydroxyethyl)-N'- [2'-(-methoxycarbonyl)thiophe |
255 |
C10H13N3O3S |
000000-00-0 |
74 |
|
3 |
Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$ |
256 |
S8 |
007704-34-9 |
60 |
|
4 |
Manganese, [{1,2-ethanediylbis [carb |
265 |
C4H6MnN2S4 |
012427-38-2 |
43 |
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Sulfur, mol. (S8)
US EPA Vial: 11 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T. 14.11 Est Conc 6.23 ug/ml or 6.23 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 Sul |
256 |
S8 |
010544-50-0 |
97 |
|
2 |
Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$ |
256 |
S8 |
007704-34-9 |
78 |
|
3 |
N-(2-Hydroxyethyl)-N'- [2'-(methoxycarbony)thiophe |
255 |
C10H13N3O3S |
000000-00-0 |
47 |
|
4 |
Manganese, [[1,2-ethanediylbis[carb |
265 |
C4H6MnN2S4 |
012427-38-2 |
47 |
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
Sulfur, mol. (S8)
US EPA Vial: 12 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T. 14.13 Est Conc 11.90 ug/ml or 11.90 ppm |
||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
|
1 |
Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 $$ Sul |
256 |
S8 |
010544-50-0 |
|
2 |
Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$ |
256 |
S8 |
007704-34-9 |
|
3 |
Manganese, [[1,2-ethanediylbis[carbamodithioato]](2 |
265 |
C4H6MnN2S4 |
012427-38-2 |
|
4 |
N-(2-Hydroxyethyl)-N'-[2'(-methoxy |
255 |
C10H13N303S |
000000-00-0 |
ON-SITE TOXIC RELEASE INVENTORIES FOR SULFURIC ACID
LEAKING TAILBRINE POND, LEAKING INJECTION WELLS, AND ENSCO INCINERATOR WASTE
Heavy metals and other contaminants in bottom ash and fly ash generated by incinerators...
COMPARING SAMPLES OF THE CAMP POND AND CAMP WATER WELL WITH CONTAMINANTS THAT HAVE BEEN FOUND IN INCINERATOR WASTE LIKE ENSCO SCRUBBER BRINE IN GLCC'S TAILBRINE POND, AND LIKE FLY ASH IN GLCC'S LANDFILLS
Silver
Nov 2003 Camp Water Well Sample contained 1.6 ug/L or 0.0016 ppm.
Aluminum
Nov 2003 Camp Water Well Sample contained 109,000 ug/L or 0.109 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 20,100.0 mg/kg or
20,100.0 ppm.
Aug 2004 Camp Water Well Sample contained 76,000 ug/L or 76 ppm.
Arsenic
Aug 2003 Camp Pond Wrist Deep Water Sample, Pathfinder Split, 7.364 ug/L or
0.007364 ppm.
Nov 2003 Camp Water Well Sample contained 22.7 ug/L or 0.22 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 7.2 mg/kg or 7.2 ppm.
Barium
Aug 2003 ADEA Camp Pond Wrist Deep Water Sample contained 0.0410 mg/L or 0.041
ppm.
Nov 2003 Camp Water Well Sample contained 931 ug/L or 0.931 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 175.0 mg/kg or 175.0
ppm.
Beryllium
Nov 2003 Camp Water Well contained 4.5 ug/L or 0.0045 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 1.5 mg/kg or 1.5 ppm.
Calcium
Aug 2003 ADEQ Surface of Pathfinder Camp Pond Water 3.9 mg/L or 3.9 ppm.
Nov 2003 Camp Water Well Sample contained 72,000 ug/L or 72.0 ppm
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 858.0 mg/kg or 858.0
ppm
Cadmium
Nov 2003 Pathfinder Camp Water Well 1.1 ug/L or 0.0011 ppm.
Nov 2003 Pathfinder Camp Dredged Sediment Sample contained 1.0 mg/kg or 1.0 ppm.
Cobalt
Nov 2003 Camp Water Well Sample contained 34.1 ug/L or 0.0341 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 9.6 mg/kg or 9.6 ppm.
Chromium
Nov 2003 Camp Water Well Sample contained 105 ug/L or 0.105 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 18.2 mg/kg or 18.2 ppm.
Copper
Nov 2003 Camp Water Well Sample contained 64.1 ug/L or 0.0641 ppm
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 8.6 mg/kg or 8.6 ppm.
Iron
Nov 2003 Camp Water Well Sample contained 82,100 ug/L or 82.1 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 22,200.0 mg/kg or
22,200.0 ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water 2.48 mg/L or 2.48 ppm.
Potassium
Nov 2003 Camp Water Well Sample contained 19,600 ug/L or 19.6 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 1,110.0 mg/kg or
1,110.0 ppm.
Magnesium
Nov 2003 Camp Water Well Sample contained 37,300 ug/L or 37.3 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 1,070.0 mg/kg or
1,070.0 ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water Sample contained 1.58 mg/L or 1.58 ppm.
Manganese
Nov 2003 Camp Water Well Sample contained 1,200 ug/L or 1.2 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 363.0 mg/kg or 363.0
ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water contained 0.358 mg/L or 0.358 ppm.
Sodium
Nov 2003 Pathfinder Camp Water Well 27,100 ug/L or 27.1 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample containted 75.9 mg/kg or 75.9 ppm.
Nickel
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 10.5 mg/kg or 10.5 ppm.
Aug 2003 Camp Water Well Sample contained 67.0 ug/L or 0.067 ppm.
Lead
Nov 2003 Camp Water Well Sample contained 76 ug/L or 0.076 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 17.5 mg/kg or 17.5 ppm.
Selenium
Nov 2003 Camp Water Well Sample contained 4.7 ug/L or 0.0047 ppm.
Vanadium
Nov 2003 Camp Water Well Sample contained 150 ug/L or 0.15 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 43.7 mg/kg or 43.7 ppm.
Zinc
Nov 2003 Camp Water Well Sample contained 306 ug/L or 0/306 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 40.4 mg/kg or 40.4 ppm.
Aug 2003 Camp Pond Wrist Deep Surface Water Sample, Pathfinder Split, 24.99 ug/L
or 0.02499 ppm.
Cadmium
Nov 2003 Pathfinder Camp Water Well 1.1 ug/L or 0.0011 ppm.
Nov 2003 Pathfinder Camp Dredged Sediment Sample contained 1.0 mg/kg or 1.0 ppm.
Mercury
Nov 2003 Camp Water Well Sample 0.33 ug/L or 0.00033 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 0.04 mg/kg or 0.04 ppm.
Docosane
Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T.
18.39 Est Conc 18.57 ug/ml, or 18.57 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
93 |
|
2 |
Docosane, 11-decyl- (CAS) $$ 11-n-Declydocosane $$ |
451 |
C32H66 |
055401-55-3 |
91 |
|
3 |
Pentacosane |
352 |
C25H52 |
000629-99-2 |
91 |
|
4 |
Docosane (CAS) $$ n-Docosane $$ C22 |
310 |
C22H46 |
000629-97-0 |
91 |
Docosane
Unknown Alkane
Retention Time 18.232
LIBRARY SEARCH COMPOUND MATCH
Heneicosane (629-94-7)
Docosane (629-97-0)
Tetratriacontane (14167-59-0
Aug 2003 Camp Pond Dredged Sediment Sample contained 580 ug/kg or 0.58 ppm.
Docosane
Unknown Alkane, Semivolatiles MS/GS Method
SW846 8270C
Retention Time 19.38
LIBRARY SEARCH COMPOUND MATCH
Heptadeocane, 9-octyl- (7225-64-1)
Decosane (696-97-00)
Nonacosane (630-03-5)
Aug 2003 Camp Pond Dredged Sediment Sample contained 1,200 ug/kg or 1.2 ppm.
Eicosane
Vial: 11- ANALYSIS OF LIBRARY SEARCH
COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED
ON DECEMBER 18, 2004
| R.T. 17.57 Est Conc 102.22 ug/ml or 102.22 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Eicosane |
282 |
C20H42 |
000112-95-8 |
96 |
|
2 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
93 |
|
3 |
Tetratetracontane |
619 |
C44H90 |
007098-22-8 |
91 |
|
4 |
Pentacosane |
352 |
C25H52 |
000629-99-2 |
91 |
Eicosane
Vial: 12 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003
CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004
| R.T. 17.57 Est Conc 41.90 ug/ml or 41.90 ppm |
||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
|
1 |
Eicosane |
282 |
C20H42 |
000112-95-8 |
|
2 |
Pentatriacontane |
493 |
C35H72 |
000630-07-9 |
|
3 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
|
4 |
Octacosane $$ n-Octacosane |
394 |
C28H58 |
000630-02-4 |
Heneicosane
Unknown Alkane
Retention Time 18.232
LIBRARY SEARCH COMPOUND MATCH
Heneicosane (629-94-7)
Docosane (629-97-0)
Tetratriacontane (14167-59-0
Aug 2003 Camp Pond Dredged Sediment Sample contained 580 ug/kg or 0.58 ppm.
Heneicosane
Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003
CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004
| R.T. 17.57 Est Conc 39.41 ug/ml or 39.41 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
95 |
|
2 |
Pentacosane |
352 |
C25H52 |
000629-99-2 |
91 |
|
3 |
Heneicosane $$ n-Heneicosane |
296 |
C21H44 |
000629-94-7 |
91 |
|
4 |
Octacosane |
394 |
C28H58 |
000630-02-4 |
91 |
Heptacosane
Unknown Alkane
Retention Time 20.47
LIBRARY SEARCH COMPOUND MATHC
Pentadecane (639-62-9)
Heptacosane (593-49-7)
Pentatriaoontane (630-07-9)
Aug 2003 Camp Pond Dredged Sediment Sample contained 1,200 ug/kg or 1.2 ppm.
Octacosane
Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND
REPORT ON NOVEMBER 20,2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18,
2004
| R.T.
17.57 Est Conc 36.61 ug/ml, or 36.61 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
95 |
|
2 |
Tetracosane |
338 |
C24H50 |
000646-31-1 |
91 |
|
3 |
Pentacosane |
352 |
C25H52 |
000629-99-2 |
91 |
|
4 |
Octacosane |
294 |
C28H58 |
000630-02-4 |
91 |
Octacosane
Vial: 8 - ANALYSIS OF LIBRARY SEARCH
COMPOUND REPORT ON NOVEMBER 20,2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON
DECEMBER 18, 2004
| R.T. 17.57 Est Conc 39.41 ug/ml or 39.41 ppm |
|||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
Qual |
|
1 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
95 |
|
2 |
Pentacosane |
352 |
C25H52 |
000629-99-2 |
91 |
|
3 |
Heneicosane $$ n-Heneicosane |
296 |
C21H44 |
000629-94-7 |
91 |
|
4 |
Octacosane |
394 |
C28H58 |
000630-02-4 |
91 |
Octacosane
Vial: 12 - ANALYSIS OF LIBRARY SEARCH
COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED
ON DECEMBER 18, 2004
| R.T. 17.57 Est Conc 41.90 ug/ml or 41.90 ppm |
||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
|
1 |
Eicosane |
282 |
C20H42 |
000112-95-8 |
|
2 |
Pentatriacontane |
493 |
C35H72 |
000630-07-9 |
|
3 |
Hexatriacontane |
507 |
C36H74 |
000630-06-8 |
|
4 |
Octacosane $$ n-Octacosane |
394 |
C28H58 |
000630-02-4 |
Octadecene
Vial: 12 - ANALYSIS OF LIBRARY SEARCH
COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED
ON DECEMBER 18, 2004
| R.T. 18.44 Est Conc 16.39 ug/ml or 16.39 ppm |
||||
|
Hit # |
Tentative ID |
MW |
Mol Form |
CAS# |
|
1 |
1-Octadecene |
252 |
C18H36 |
000112-88-9 |
|
2 |
9-Nonadecene |
266 |
C19H38 |
031035-07-1 |
|
3 |
Octadecanol |
270 |
C18H380 |
026762-44-7 |
|
4 |
1-Dotriacontanol $$ n-Dotriacontano |
467 |
C32H660 |
006624-79-9 |
GREAT LAKES CHEMICAL CORPORATION (CHEMTURA) AND THE PATHFINDERS CAMP