Comparison of GLCC

Comparison of GLCC's Buffing Dust and other GLCC Toxic Materials from the Cylinder Prep Area and Analysis of Samples from Camp Pond and Camp Water Well

When it rains, buffing dust and other GLCC toxic materials migrates off-site through this hole and flows southwest along the railroad tracks. This toxic fluid contains ingredients from GLCC products like: flame retardants, and waste products like: chemical coatings, labels, adhesives, solvents, strapping tape, steel cylinders, steel shot or steel grit abrasives, and other GLCC toxic materials. It rains a lot.

About 20 feet below the surface of the ground here is the first aquifer, which is called the Interbedded Unit (IBU). The elevation of the IBU in the area of the above picture is approximately 280 to 300 feet. The elevation of the IBU at the Camp Pond is approximately 240 feet. This toxic fluid soaks into the IBU and flows southwest in the IBU to feed the spring fed Camp Pond.

This toxic fluid contains ingredients from GLCC products like: flame retardants, and waste products like: chemical coatings, labels, adhesives, solvents, strapping tape, steel cylinders, steel shot or steel grit abrasives, and other GLCC toxic materials.

GLCC PRODUCTS LIKE: FLAME RETARDANTS

The EPA took some core samples from the Camp Pond Sediment in July 1977. Analysis of these core samples shows detection of Tetrabromobisphenol A (Synonym: 4,4'-ISOPROPYLIDENEDIPHENOL) at 300 ug/Kg or 0.003 ppm.

Tetrabromobisphenol A is a flame retardant made at GLCC-Central.

ON-SITE TOXIC RELEASE INVENTORIES FOR TETRABROMOBISPHENOL A AT GLCC-CENTRAL

ON-SITE TOXIC RELEASE INVENTORIES FOR 4,4'-ISOPROPYLIDENEDIPHENOL AT GLCC-CENTRAL

Stigmasterol
Unknown
Semivolatiles MS/GS Method SW846 8270C
Retention Time 21.886
Stigmasterol (83-48-7) C29H480
Bis(pentaamethylcyclopentadienyl) iron (12126-50-0) C20H330Fe
.alpha. Bioyolo-octan(1-6,2-3)cyclohen-1 (33495-95-3) C22H3002
Aug 2003 Camp Pond Dredged Sediment Pathfinder Sample contained 2,100.0 ug/kg or 2.1 ppm.

STIGMASTEROL AND FIRE RETARDANT

Stigmasterol
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 19.95 Est Conc 74.62 ug/ml or 74.62 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Stigmasterol, 22, 23-dihydro-	414	C29H500	000000-00-0	99
2	.beta.-Sitosterol	414	C29H500	000083-46-5	86
3	17-(1,5-Dimethylhexyl)-10, 13-dimethyl-4-vinylhexade	414	C29H500	000000-00-0	70
4	.gamma.-Sitosterol $$ Stigmast-5-en	414	C29H500	000083-47-6	64

STIGMASTEROL AND FIRE RETARDANT

Stigmasterol
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 19.95 Est Conc 42.69 ug/ml or 42.69 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	.gamma.-Sitosterol	414	C29H500	000083-47-6	99
2	Stigmasterol, 22,23-dihydro-	414	C29H500	000000-00-0	96
3	17-(1,5-Dimethylhexyl) -10,13-dimethyl-4-vinylhexade	414	C29H500	000000-00-0	86
4	.beta.-Sitosterol	414	C29H500	000083-46-5	55

STIGMASTEROL AND FIRE RETARDANT

Stigmasterol
US EPA Vial: 11 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 19.96 Est Conc 107.14 ug/ml or 107.14 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	.gamma.-Sitosterol	414	C29H500	000083-47-6	99
2	Stigmasterol, 22,23-dihydro-	414	C29H500	000000-00-0	96
3	.beta.Sitosterol	414	C29H500	000083-46-5	86
4	Cholest-7-en-3-ol, 4,4-dimethyl-, (	414	C29H500	006384-28-7	64

STIGMASTEROL AND FIRE RETARDANT

Stigmasterol
US EPA Vial: 12 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 19.95 Est Conc 42.84 ug/ml or 42.84 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#
1	.gamma.-Sitosterol	414	C29H500	000083-47-6
2	Stigmasterol, 22,23-dihydro	414	C29H500	000000-00-0
3	.beta.-Sitosterol	414	C29H500	000083-46-5
4	17-(1,5-Dimethylhexyl)-10, 13-dimeth	414	C29H500	000000-00-0

STIGMASTEROL AND FIRE RETARDANT

Unknown e (10191-41-0)
DL-ALPHA-TOCOPHEROL (10191-41-0)
Nov 2003 EPA Camp Pond Sediment Sample contained 2,300 ug/kg or 2.3 ppm.
There is a relationship between Alpha Tocopherol (Vitamin E), Soybeans, and Flame Retardants.

Vitamin e
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 18.73 Est Conc 17.32 ug/ml or 17.32 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Vitamin e $$ d1-.alpha.-Tocopherol $$ 2H-Benzopyr	430	C29H5002	010191-41-0	98
2	Vitamin E $$ 2H-1-Benzopyran-6-o1, 3,4-dihydro-2,5,	430	C29H5002	000059-02-9	93
3	Benzenamine, 3-methoxy-2,4,6-trimethyl- $$ Methoxym	165	C10H15NO	034874-88-9	47
4	Propanenitrile, 3[methyl (4-nitroph	205	C10H11N3O2	097473-81-9	47

There is a relationship between Alpha Tocopherol (Vitamin E), Soybeans, and Flame Retardants.

Vitamin e
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 18.72 Est Conc 15.77 ug/ml or 15.77 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Vitamin e	430	C29H5002	010191-41-0	98
2	Vitamin E $$ 2H-1-Benzopyran-6-o1	430	C29H5002	000059-02-9	93
3	.alpha.-Tocopherol- .beta.-D-mannosi	592	C35H6007	000000-00-0	78
4	2-Amino-8-methylimidazo [1,5-al] -1,3	165	C6H7N50	070187-88-1	50

There is a relationship between Alpha Tocopherol (Vitamin E), Soybeans, and Flame Retardants.

Vitamin e
US EPA Vial: 11 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 18.73 Est Conc 25.14 ug/ml or 25.14 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Vitamin e $$ d1-.alpha.-Tocopherol $$ 2H-Benzopyr	430	C29H5002	010191-41-0	99
2	Vitamin E $$ 2H-1-Benzopyran-6-ol, 3,4-dihydro-2,5,	430	C29H5002	000059-02-9	93
3	.alpha.Tocopherol-.beta. -D-mannosi	592	C35H6007	000000-00-0	90
4	2-Amino-8-methylididazo [1,5-a]-1.3	165	C6H7N5O	070187-88-1	50

There is a relationship between Alpha Tocopherol (Vitamin E), Soybeans, and Flame Retardants.

Benzoic Acid
Aug 2003 Camp Pond Sediment 84.98 ug/kg or 0.08498 ppm.
Benzoic Acid and Velsicol and Flame Retartants and Pesticides and so on...

Ammonia
Aug 2004 Pathfinder Camp Water Well Sample contained 0.0958 mg/L or 0.0958 ppm.
Ammonia and Fire Retardant

TOXIC RELEASE INVENTORIES FOR AMMONIA AT GLCC CENTRAL

Zinc
Nov 2003 Camp Water Well Sample contained 306 ug/L or 0.306 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 40.4 mg/kg or 40.4 ppm.
Aug 2003 Camp Pond Wrist Deep Surface Water Sample, Pathfinder Split, 24.99 ug/L or 0.02499 ppm.

ZINC AND FLAME RETARDANT

ON-SITE TOXIC RELEASE INVENTORIES FOR ZINC AT GLCC-CENTRAL

Tetrachloroethylene
Aug 2004 Camp Water Well Sample contained 19,000.0 ug/L or 19.0 ppm.
Tetrachloroethylene and Flame Retardant

Trichloroethylene
Aug 2004 Camp Water Well Sample contained 144.0 ug/L or 0.144 ppm.

1,1'-Biphenyl, bis(methylethyl)- (69009-90-1)
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 3,000 ug/kg or 3.0 ppm.

INGREDIENTS IN PAINT (CHEMICAL COATINGS)
Information about Chemical Coatings

3-Penten-2-one, 4-methyl-oxide (141-79-7)
Synonym: MESITYL OXIDE
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES,
RECEIVED ON DECEMBER 18, 2004

R.T. 4.20 Est Conc 250.79 ug/ml or 250.79 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	3-Penten-2-one, 4-methyl-oxide $$	98	C6H100	000141-79-7	94
2	3-Hexen-2-one	98	C6H100	000763-93-9	90
3	2-Pentene, 3, 4-dimethyl-, (Z)-	98	C7H14	004914-91-4	86
4	tert-Butylketene $$ 1-Buten-1-one	98	C6H100	059005-31-1	80

MESITYL OXIDE USES: Manufacture of methyl isobutyl ketone; solvent; ore flotation; insect repellent; paint and varnish remover.

3-Penten-2-one (141-79-7)
Synonym: MESITYL OXIDE
US EPA Vial: 11- ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 4.20 Est Conc 181.75 ug/ml or 181.75 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	3-Penten-2-one	98	C6H100	000141-79-7	95
2	3-Hexen-2-one	98	C6H100	000763-93-9	91
3	2(3H)-Furanone, 5-methyl- (CAS) $$	98	C5H602	000591-12-8	91
4	2-Pentene, 3,4-dimethyl-, (E)-$$	98	C7H14	004914-92-5	90

MESITYL OXIDE USES: Manufacture of methyl isobutyl ketone; solvent; ore flotation; insect repellent; paint and varnish remover.

Ethylbenzene (100-41-4)
Nov 2003 Camp Water Well Sample contained 0.3981 ug/L or 0.0003981 ppm.
Aug 2004 Camp Water Well Sample contained 37.0 ug/L or 0.037 ppm.
Information Regarding Ethylbenzene and Paint and Coatings

Oxirane, hexadecyl- (7390-81-0)
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 19.13 Est Conc 16.57 ug/ml or 16.57 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Oxirane, hexadecyl-	268	C18H360	007390-81-0	90
2	Octadecanal	268	C18H360	000628-66-4	87
3	Oxirane, heptadecyl- $$ 1,2-Epoxynonadecane	282	C19H380	067860-04-2	72
4	Hexadecanal	240	C16H320	000629-80-1	64

Oxirane, hexadecyl- (7390-81-0): Synonym: 1,2-EPOXYOCTADECANE , which is an ingredient in epoxy coatings.

Oxirane, heptadecyl- $$ 1,2-Epoxynonadecane
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 19.12 Est Conc 14.69 ug/ml or 14.69 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Oxirane, heptadecyl- $$ 1,2-Epoxynonadecane	282	C19H380	067860-04-2	93
2	Octadecanal	268	C18H360	000638-66-4	91
3	Hexadecanal	240	C16H320	000628-80-1	90
4	Oxirane, heptadecyl- $$ 1,2-Epoxyoct	268	C18H360	007390-81-0	86

1,2-EPOXYOCTADECANE is an ingredient in epoxy coatings.

OXIRANE is in paint and/or epoxy coatings.

Acetone
Aug 2003 Camp Pond Dredged Sediment Sample contained 21.0 ug/kg or 0.021 ppm.
Nov 2003 Pathfinder Camp Water Well Sample contained 5.707 ug/L or 0.007707 ppm.
Information Regarding Acetone and Adhesive

Xylene
o-Xylene (95-47-6)
November 2003 Camp Water Well Sample contained 1.226 ug/L or 0.01226 ppm.
m-Xylene & p-Xylene (1336777-62-2)
Nov 2003 Camp Water Well Sample contained 0.5749 ug/L or 0.000574 ppm.
Nov 2003 Total Xylene in Pathfinder Camp Water Well 1.7789 ug/L or 0.017789 ppm.
Information Regarding Xylene, Paint, and Coatings

Methyl Acetate
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 351ug/kg or 0.351 ppm.
Information Regarding Methyl Acetate and Paint

2-Butanone
Synonym: Methyl Ethyl Ketone
Aug 2003 Pathfinder Camp Pond Sediment 6.3 ug/kg or 0.0063 ppm.
Information Regarding 2-Butanone, Paint, and Coatings

Isoamyl Alcohol
Aug 2004 Camp Water Well Sample contained 50.0 ug/L or 0.05 ppm.
Isoamyl Alcohol and Paint

Carbon disulfide
Retention Time 4.517
Nov 2003 Pathfinder Camp Water Well Sample contained 3.062 ug/L or 0.003062 ppm.
INFORMATION REGARDING CARBON DISULFIDE AND PAINT

Chloroform (67-66-3)
Nov 2003 Pathfinder Camp Water Well Sample contained 0.5246 ug/L or 0.0005246 ppm.
INFORMATION REGARDING CHLOROFORM AND PAINT

Pentachlorophenol
Nov 2003 EPA Camp Pond Sediment Sample contained 1090 ug/kg or 1.09 ppm.
Information Regarding Pentachlorophenol and Paint

1,1'-Biphenyl, bis(methylethyl)- (69009-90-1)
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 3,000 ug/kg or 3.0 ppm.
It is an ingredient in Plastic and Vinyl Bonding Primer (Paint).

n-Butyl Alcohol
Aug 2004 Camp Water Well Sample contained 3220.0 ug/L or 3.22 ppm.

n-Butyl Alcohol is an ingredient in "SOLVENT THINNED PAINT."

ON-SITE TOXIC RELEASE INVENTORIES FOR n-Butyl Alcohol AT GLCC-CENTRAL

7,12-dimethyl-1,2-epoxy- 1,2,3,4-tetrahydrobenz[a]an
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 16.84 Est Conc 24.23 ug/ml or 24.23 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	7,12-dimethyl-1,2-epoxy- 1,2,3,4-tetrahydrobenz[a]an	274	C20H18O	000000-00-0	83
2	Quinazoline, 2-phenyl-4- (1H-tetrazol-5-y)- (CAS) $	274	C15H10N6	067824-29-7	59
3	(Z)-2,3-dihydro- 1H-cylonona[def]diphenylene	218	C17H14	104642-23-1	55
4	1H-Cyclopenta[1]phenanthrene, 2,3-d	218	C17H14	000723-98-8	46

POTENTIALLY IN EPOXY COATINGS

5,6,6a,11a-tetrahydro-5, 11a-epoxy-11H-benzo[a]fluor (114325-52-9)
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 20.03 Est Conc 22.66 ug/ml or 22.66 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	2,7-Dimethyl-3,5-dimethylio-2H- 1,2,4-triazepine	215	C8H13N3S2	000000-00-0	25
2	5,6,6a,11a-tetrahydro-5, 11a-epoxy-11H-benzo[a]fluor	234	C17H140	114325-52-9	22
3	(3a.alpha., 2.beta., 5.beta.,6.alpha., 9a.beta.10a.b	360	C16H25IO	097719-20-5	16
4	1(2H)-Naphthalenone, 3,4-dihydro-2-	234	C17H140	006261-32-1	14

POTENTIALLY IN EPOXY COATINGS

Phenanthrene, 1-methyl-7-(1-methylethyl)- (483-65-8)
Synonym: Retene
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 40,000 ug/kg or 40.0 ppm.
Information Regarding Phenanthrene, 1-methyl-7-(1-methylethyl)-

Retene is in Diesel (#2) Fuel Oil.

POTENTIALLY IN EPOXY COATINGS

Phenanthrene, 1-methyl-7-(1-methylethyl)- (483-65-8)
US EPA Vial: 11- ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON
NOVEMBER 20,2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 14.91 Est Conc 251.23 ug/ml or 251.23 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Phenanthrene, 1-methyl-7-(1-methyl)-(CAS) $$	234	C18H18	000483-65-8	96
2	(E,E)-2,5-Diphenyl-2,4-hexadiene	234	C18H18	016914-12-8	91
3	12,17-epoxy- 13,14,15,16-tetranorlab-8(17)-one	234	C16H260	000000-00-0	90
4	3-methyl-4,5-diphenylpyrazole	234	C16H14N2	000000-00-0	70

Information Regarding Phenanthrene, 1-methyl-7-(1-methylethyl)-

Retene is in Diesel (#2) Fuel Oil.

POTENTIALLY IN EPOXY COATINGS

Unknown aldehyde or oxirane
Retention Time 19.12
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 2,000.0 ug/kg or 2.0 ppm.
POTENTIALLY IN EPOXY COATINGS

OXIRANE is in paint and/or epoxy coatings.

Aldehyde is used for ink and paint.

Unknown aldehyde or oxirane
Retention Time 19.13
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 3,700.0 ug/kg or 3.7 ppm.
POTENTIALLY IN EPOXY COATINGS

OXIRANE is in paint and/or epoxy coatings.

Aldehyde is used for ink and paint.

2-Pentanone, 4-hydroxy-4-methyl (123-43-2)
Synonym: Diacetone Alcohol

Unknown Aldol Condensate
Retention Time 3.092
LIBRARY SEACH COMPOUND MATCH
2-Pentanone, 4-hydroxy-4-methyl (123-43-2) Synonym: Diacetone Alcohol
Acetic acid, 1,1-dimethylethyl ester (540-88-5)
Acedic acid, Cyano-, 1,1-dimethylethyl (1116-98-9)
Aug 2003 Camp Pond Dredged Sediment contained 22,000 ug/kg or 22.0 ppm.
Diacetone Alcohol is in paint

2-Pentanone, 4-hydroxy-4-methyl (123-42-2)
Synonym: Diacetone Alcohol
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 4.72 Est Conc 159.42 ug/ml, or 159.42 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	2-Pentanone, 4-hydroxy-4-methyl (CAS) $$ Diacetone	116	C6H1202	000123-42-2	83
2	Acetic acid, 1-1-dimethylethyl ester $$ Acetic Acid	116	C6H1202	000540-88-5	33
3	DIETHYLAMINE-D1	74	C4H1202	000997-11-5	28
4	3-Pentanol $$ Diethyl carbinol $$ 3	88	C5H120	000584-02-1	28

Diacetone Alcohol is in paint.

Oleic Acid (112-80-1)
Unknown Organic Acid
Retention Time 14.546
LIBRARY SEARCH COMPOUND MATCH
Oleic Acid (112-80-1)
15-Tetracosenoic acid, methyl ester, (Z) (2733-88-2)
9-Hexadecenoic acid (2091-29-4)
Aug 2003 Camp Pond Dredged Sediment Sample contained 1,300.0 ug/kg or 1.3 ppm.
Oleic Acid and Paint

Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S (10544-50-0)
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 14.13 Est Conc 17.43 ug/ml, or 17.43 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S	256	S8	010544-50-0	95
2	Manganese, [[1,2-ethanediylbis[carbamodithioato]](2	265	C4H6MnN2S4	012427-38-2	90
3	Sulfur $$ Sulfur, precipitated $$ S	256	S8	007704-38-9	72
4	N-(2-Hydroxyethyl)-N'-[2'-(methoxy	255	C10H13N3O3S	000000-00-0	64

Sulfur is in paint.

Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S (10544-50-0)
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 14.11 Est Conc 8.28 ug/ml or 8.28 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Sulfur, mol (S8) (CAS) $$ OCTA -SULFUR $$ s8 $$ Sul	256	S8	010544-50-0	97
2	N-(2-Hydroxyethyl)-N'- [2'-(-methoxycarbonyl)thiophe	255	C10H13N3O3S	000000-00-0	74
3	Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$	256	S8	007704-34-9	60
4	Manganese, [{1,2-ethanediylbis [carb	265	C4H6MnN2S4	012427-38-2	43

Sulfur is in paint.

Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S (10544-50-0)
US EPA Vial: 11 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 14.11 Est Conc 6.23 ug/ml or 6.23 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 Sul	256	S8	010544-50-0	97
2	Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$	256	S8	007704-34-9	78
3	N-(2-Hydroxyethyl)-N'- [2'-(methoxycarbony)thiophe	255	C10H13N3O3S	000000-00-0	47
4	Manganese, [[1,2-ethanediylbis[carb	265	C4H6MnN2S4	012427-38-2	47

Sulfur is in paint.

Sulfur, mol. (S8) (CAS) OCTA-SULFUR $$ S8 $$ S (10544-50-0)
US EPA Vial: 12 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 14.13 Est Conc 11.90 ug/ml or 11.90 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#
1	Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 $$ Sul	256	S8	010544-50-0
2	Sulfur $$ Sulfur, precipitated $$ S $$ Brimstone $$	256	S8	007704-34-9
3	Manganese, [[1,2-ethanediylbis[carbamodithioato]](2	265	C4H6MnN2S4	012427-38-2
4	N-(2-Hydroxyethyl)-N'-[2'(-methoxy	255	C10H13N303S	000000-00-0

Sulfur is in paint.

Unknown Sulfur Compound
Retention Time 10.78
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 2,900 ug/kg or 2.9 ppm.
Sulfur is in paint.

Unknown Sulfur Compound
Retention Time 10.85
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 2,700.0 ug/kg or 2.7 ppm.
Sulfur is in paint.

Unknown Sulfur Compound
Retention Time 10.89
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 3,600.0 ug/kg or 3.6 ppm.
Sulfur is in paint.

Cyclic octaatomic sulfur (10544-50-0) S8
Aug 2003 Camp Pond Sediment Sample contained 9,300 ug/kg or 9.3 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 25,000 ug/kg or 25.0 ppm.
Sulfur is in paint.

INGREDIENTS IN LABELS

Unknown aldehyde or oxirane
Retention Time 19.12
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 2,000.0 ug/kg or 2.0 ppm. Aldehyde is used for ink and paint.

Unknown aldehyde or oxirane
Retention Time 19.13
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 3,700.0 ug/kg or 3.7 ppm. Aldehyde is used for ink and paint.

Di-n-butyl-phthalate
synonym: Dibutyl Phthalate
Aug 2003 Camp Pond Wrist Deep Surface Water ADEQ Sample contained 2.47 ug/L or 0.0027 ppm.
INFORMATION REGARDING DIBUTYL PHTHALATE AND PRINTING INKS AND PAPER COATINGS

INGREDIENTS IN ADHESIVES

Methyl Acetate
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 351ug/kg or 0.351 ppm.
Information Regarding Methyl Acetate and Adhesive

2-Butanone
Synonym: Methyl Ethyl Ketone
Aug 2003 Pathfinder Camp Pond Sediment 6.3 ug/kg or 0.0063 ppm.
Information Regarding 2-Butanone and Adhesive

Carbon disulfide
Retention Time 4.517
Nov 2003 Pathfinder Camp Water Well Sample contained 3.062 ug/L or 0.003062 ppm.
INFORMATION REGARDING CARBON DISULFIDE AND ADHESIVE

Di-n-butyl-phthalate
synonym: Dibutyl Phthalate
Aug 2003 Camp Pond Wrist Deep Surface Water ADEQ Sample contained 2.47 ug/L or 0.0027 ppm.
INFORMATION REGARDING DIBUTYL PHTHALATE AND ADHESIVE

Chloroform (67-66-3)
Nov 2003 Pathfinder Camp Water Well Sample contained 0.5246 ug/L or 0.0005246 ppm.
INFORMATION REGARDING CHLOROFORM AND ADHESIVE

Pentachlorophenol
Nov 2003 EPA Camp Pond Sediment Sample contained 1090 ug/kg or 1.09 ppm.
Information Regarding Pentachlorophenol and Adhesive

INGREDIENTS IN STRAPPING TAPE

INGREDIENTS IN SOLVENTS

Methyl Acetate
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 351ug/kg or 0.351 ppm.
Information Regarding Methyl Acetate and Solvent

2-Butanone
Synonym: Methyl Ethyl Ketone
Aug 2003 Pathfinder Camp Pond Sediment 6.3 ug/kg or 0.0063 ppm.
Information Regarding 2-Butanone and Solvent

Carbon disulfide
Retention Time 4.517
Nov 2003 Pathfinder Camp Water Well Sample contained 3.062 ug/L or 0.003062 ppm.
INFORMATION REGARDING CARBON DISULFIDE AND SOLVENT

Di-n-butyl-phthalate
synonym: Dibutyl Phthalate
Aug 2003 Camp Pond Wrist Deep Surface Water ADEQ Sample contained 2.47 ug/L or 0.0027 ppm.
INFORMATION REGARDING DIBUTYL PHTHALATE AND SOLVENT

Chloroform (67-66-3)
Nov 2003 Pathfinder Camp Water Well Sample contained 0.5246 ug/L or 0.0005246 ppm.
IFORMATION REGARDING CHLOROFORM AND SOLVENT

Isoamyl Alcohol
Aug 2004 Camp Water Well Sample contained 50.0 ug/L or 0.05 ppm.
Isoamyl Alcohol and Solvent

Eicosane (112-95-8)
US EPA Vial: 11 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 EPA CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 17.57 Est Conc 102.22 ug/ml or 102.22 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Eicosane	282	C20H42	000112-95-8	96
2	Hexatriacontane	507	C36H74	000630-06-8	93
3	Tetratetracontane $$ Tetratetracontane	619	C44H90	007098-22-8	91
4	Pentacosane	352	C25H52	000629-99-2	91

Eicosane is a solvent.

3-Penten-2-one, 4-methyl-oxide
Synonym: Mesityl oxide (141-79-7)
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 EPA CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 4.20 Est Conc 250.96 ug/ml or 250.96 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	3-Penten-2-one, 4-methyl-oxide $$	98	C6H100	000141-79-7	94
2	3-Hexen-2-one	98	C6H100	000763-93-9	90
3	2-Pentene, 3, 4-dimethyl-, (Z)-	98	C7H14	004914-91-4	86
4	tert-Butylketene $$ 1-Buten-1-one	98	C6H100	059005-31-1	80

MESITYL OXIDE AND PAINT REMOVER (SOLVENT)

4-HYDROXY-4-METHYL-2-PENTANONE (123-42-2)
Synonym : DIACETONALCOHOL
US EPA Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 EPA CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 4.72 Est Conc 176.75 ug/ml, or 176.75 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	2-Pentanone, 4-hydroxy-4-methyl (CAS) $$ Diacetone	116	C6H1202	000123-42-2	83
2	Acetic acid, 1-1-dimethylethyl ester $$ Acetic Acid	116	C6H1202	000540-88-5	33
3	DIETHYLAMINE-D1	74	C4H1202	000997-11-5	28
4	3-Pentanol $$ Diethyl carbinol $$ 3	88	C5H120	000584-02-1	28

4-HYDROXY-4-METHYL-2-PENTANONE (123-42-2) AND PAINT SOLVENT

Trichloroethylene
Aug 2004 Camp Water Well Sample contained 144.0 ug/L or 0.144 ppm
Trichloroethylene is a solvent.

Tetrachloroethylene
Aug 2004 Camp Water Well Sample contained 19,000.0 ug/L or 19.0 ppm.
Tetrachloroethylene is a solvent.

n-Butyl Alcohol
Aug 2004 Camp Water Well Sample contained 3220.0 ug/L or 3.22 ppm.
n-Butyl alcohol is a solvent.

Hexatriacontane (630-06-8)
US EPA Vial: 4 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 17.57 Est Conc 36.61 ug/ml, or 36.61 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	Hexatriacontane	507	C36H74	000630-06-8	95
2	Tetracosane	338	C24H50	000646-31-1	91
3	Pentacosane	352	C25H52	000629-99-2	91
4	Octacosane	294	C28H58	000630-02-4	91

Hexatriacontane is a solvent and an ingredient in diesel fuel.

INGREDIENTS IN STEEL CYLINDERS

INGREDIENTS IN STEEL SHOT OR STEEL GRIT ABRASIVES

Iron
Nov 2003 Camp Water Well Sample contained 82,100 ug/L or 82.1 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 22,200.0 mg/kg or 22,200.0 ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water 2.48 mg/L or 2.48 ppm.

Manganese
Nov 2003 Camp Water Well Sample contained 1,200 ug/L or 1.2 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 363.0 mg/kg or 363.0 ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water contained 0.358 mg/L or 0.358 ppm.

Chromium
Nov 2003 Camp Water Well Sample contained 105 ug/L or 0.105 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 18.2 mg/kg or 18.2 ppm.

Nickel
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 10.5 mg/kg or 10.5 ppm.
Aug 2003 Camp Water Well Sample contained 67.0 ug/L or 0.067 ppm.

Aluminum
Nov 2003 Camp Water Well Sample contained 109,000 ug/L or 0.109 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 20,100.0 mg/kg or 20,100.0 ppm.
Aug 2004 Camp Water Well Sample contained 76,000 ug/L or 76 ppm.

Arsenic
Aug 2003 Camp Pond Wrist Deep Water Sample, Pathfinder Split, 7.364 ug/L or 0.007364 ppm.
Nov 2003 Camp Water Well Sample contained 22.7 ug/L or 0.22 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 7.2 mg/kg or 7.2 ppm.

Cadmium
Nov 2003 Pathfinder Camp Water Well 1.1 ug/L or 0.0011 ppm.
Nov 2003 Pathfinder Camp Dredged Sediment Sample contained 1.0 mg/kg or 1.0 ppm.

Cobalt
Nov 2003 Camp Water Well Sample contained 34.1 ug/L or 0.0341 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 9.6 mg/kg or 9.6 ppm.

Copper
Nov 2003 Camp Water Well Sample contained 64.1 ug/L or 0.0641 ppm
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 8.6 mg/kg or 8.6 ppm.

Lead
Nov 2003 Camp Water Well Sample contained 76 ug/L or 0.076 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 17.5 mg/kg or 17.5 ppm.

Magnesium
Nov 2003 Camp Water Well Sample contained 37,300 ug/L or 37.3 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 1,070.0 mg/kg or 1,070.0 ppm.
Aug 2003 ADEQ Camp Pond Wrist Deep Water Sample contained 1.58 mg/L or 1.58 ppm.

Potassium
Nov 2003 Camp Water Well Sample contained 19,600 ug/L or 19.6 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 1,110.0 mg/kg or 1,110.0 ppm.

Sodium
Nov 2003 Pathfinder Camp Water Well 27,100 ug/L or 27.1 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample containted 75.9 mg/kg or 75.9 ppm.

Selenium
Nov 2003 Camp Water Well Sample contained 4.7 ug/L or 0.0047 ppm.

Vanadium
Nov 2003 Camp Water Well Sample contained 150 ug/L or 0.15 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 43.7 mg/kg or 43.7 ppm.

Zinc
Nov 2003 Camp Water Well Sample contained 306 ug/L or 0/306 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 40.4 mg/kg or 40.4 ppm.
Aug 2003 Camp Pond Wrist Deep Surface Water Sample, Pathfinder Split, 24.99 ug/L or 0.02499 ppm.

Unknown Sulfur Compound
Retention Time 10.78
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 2,900 ug/kg or 2.9 ppm.

Unknown Sulfur Compound
Retention Time 10.85
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 2,700.0 ug/kg or 2.7 ppm.

Unknown Sulfur Compound
Retention Time 10.89
Nov 2003 EPA Camp Pond Dredged Sediment Sample contains 3,600.0 ug/kg or 3.6 ppm.

Cyclic octaatomic sulfur (10544-50-0) S8
Aug 2003 Camp Pond Sediment Sample contained 9,300 ug/kg or 9.3 ppm.
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 25,000 ug/kg or 25.0 ppm.

LIKELY OTHER GLCC TOXIC MATERIALS

cis-1,2-Dichloroethane
Synonym: Ethylene Dichloride
Aug 2004 Camp Water Well Sample contained 1010 ug/L or 1.01 ppm.

trans-1,2-Dichloroethane
Synonym: Ethylene Dichloride
Aug 2004 Camp Water Well Sample contained 34.0 ug/L or 0.034 ppm.

2-Butanone
Synonym: Methyl Ethyl Ketone
Aug 2003 Pathfinder Camp Pond Sediment 6.3 ug/kg or 0.0063 ppm.

Bromide
August 2003 ADEQ Surface of Camp Pond Water contained 0.77mg/L or 0.77 ppm.
August 2004 Camp Water Well Sample contained 0.37 mg/L or 0.37 ppm

Ammonia
Aug 2004 Pathfinder Camp Water Well Sample contained 0.0958 mg/L or 0.0958 ppm.

Trichloroethylene
Aug 2004 Camp Water Well Sample contained 144.0 ug/L or 0.144 ppm.
Manufacturing/Use Information

1,1-Biphenyl, 5,2',3,4-tetramethoxy
Vial: 8 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 16.83 Est Conc 14.00 ug/ml or 14.00 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#	Qual
1	1,1-Biphenyl, 5,2',3,4-tetramethoxy	274	C16H1804	000000-00-0	56
2	2,9-Dibora- 1,3,5,7-tetraoxaphenanthrene-4, 8-dione	274	C12H12B206	000000-00-0	50
3	1H-Cyclopenta[1]phenanthrene, 2,3-dihydro-	218	C17H14	000723-98-8	49
4	Naphthalene, 2-(Phenylmethyl)-	218	C17H14	000613-59-2	46

2(1H) - Naphthalenone, 4,4a,5,6,7,8-hexahydro-4,8a-dim
Vial: 12 - ANALYSIS OF LIBRARY SEARCH COMPOUND REPORT ON NOVEMBER 20, 2003 CAMP POND SEDIMENT SAMPLES, RECEIVED ON DECEMBER 18, 2004

R.T. 20.46 Est Conc 17.00 ug/ml or 17.00 ppm
Hit #	Tentative ID	MW	Mol Form	CAS#
1	2(1H) - Naphthalenone, 4,4a,5,6,7,8-hexahydro-4,8a-dim	218	C15H220	086941-63-1
2	2(3H) -Naphthalenone, 4,4a,5,6,7,8-hexahydro-4a,5-di	218	C17H14	019589-45-9
3	Naphthalene, 2-(phenylmethyl)- $$ Naphthalene,2-be	218	C17H14	000613-59-2
4	(4R,4aS,6S) -6-Isopropenyl-4, 4a-dime	218	C15H220	053768-26-6

1Hcycolopenta[1] phenanthrene, 2,3-dihydr (723-98-8)
LIBRARY SEARCH COMPOUND MATCH
1Hcycolopenta[1] phenanthrene, 2,3-dihydr (723-98-8) C17H14
2,9-Dibora- 1,3,5,7-tetraoxaphenanthrene- (1000159-66-2) C12H12B206
Naphthalene, 2-(phenylmethyl)- (613-59-2) C17H14
Aug 2003 Camp Pond Dredged Sediment Sample contained 1,800 ug/kg or 1.8 ppm.

2-Butanol, 3-methyl, acetate (5343-96-4)
Nov 2003 EPA Camp Pond Dredged Sediment Sample contained 4,100.0 ug/kg or 4.1 ppm.
2-Butanol, 3-methyl, acetate (5343-96-4)

2-(3-Chlorophenyl)ethylamine (13078-79-0)
Aug 2003 Camp Pond Sediment Sample contained 790 ug/kg or 0.79 ppm.
2-(3-Chlorophenyl)ethylamine (13078-79-0)

cis-1,2-Dichloroethane
Synonym: Ethylene Dichloride
Aug 2004 Camp Water Well Sample contained 1010 ug/L or 1.01 ppm.
Ethylene dichloride and Ethylene dibromide

trans-1,2-Dichloroethane
Synonym: Ethylene Dichloride
Aug 2004 Camp Water Well Sample contained 34.0 ug/L or 0.034 ppm.
Ethylene dichloride and Ethylene dibromide

HAZARDOUS MATERIALS IN PAINT (CHEMICAL COATINGS)

INGREDIENTS IN 3M SUPER 77 MULTIPURPOSE ADHESIVE

GREAT LAKES CHEMICAL CORPORATION (CHEMTURA) AND THE PATHFINDERS CAMP